Joseph Priestley

Priestley was born to an established English Dissenting family (i.e. they did not conform to the Church of England) in Birstall, near Batley in the West Riding of Yorkshire. He was the oldest of six children born to Mary Swift and Jonas Priestley, a finisher of cloth. To ease his mother's burdens, Priestley was sent to live with his grandfather around the age of one. He returned home, five years later, after his mother died. When his father remarried in 1741, Priestley went to live with his aunt and uncle, the wealthy and childless Sarah and John Keighley, 3 miles (4.8 km) from Fieldhead. Because Priestley was precocious—at the age of four he could flawlessly recite all 107 questions and answers of the Westminster Shorter Catechism—his aunt sought the best education for the boy, intending him for the ministry. During his youth, Priestley attended local schools where he learned Greek, Latin, and Hebrew.

Discovery of oxygen

In August 1774 he isolated an "air" that appeared to be completely new, but he did not have an opportunity to pursue the matter because he was about to tour Europe with Shelburne. While in Paris, however, Priestley managed to replicate the experiment for others, including French chemist Antoine Lavoisier. After returning to Britain in January 1775, he continued his experiments and discovered "vitriolic acid air" (sulphur dioxide, SO2).

In March he wrote to several people regarding the new "air" that he had discovered in August. One of these letters was read aloud to the Royal Society, and a paper outlining the discovery, titled "An Account of further Discoveries in Air", was published in the Society's journal Philosophical Transactions. Priestley called the new substance "dephlogisticated air", which he made in the famous experiment by focusing the sun's rays on a sample of mercuric oxide. He first tested it on mice, who surprised him by surviving quite a while entrapped with the air, and then on himself, writing that it was "five or six times better than common air for the purpose of respiration, inflammation, and, I believe, every other use of common atmospherically air". He had discovered oxygen gas (O2).

Volume I of Experiments and Observations on Different Kinds of Air outlined several discoveries: "nitrous air" (nitric oxide, NO); "vapor of spirit of salt", later called "acid air" or "marine acid air" (anhydrous hydrochloric acid, HCl); "alkaline air" (ammonia, NH3); "diminished" or "dephlogisticated nitrous air" (nitrous oxide, N2O); and, most famously, "dephlogisticated air" (oxygen, O2) as well as experimental findings that showed plants revitalised enclosed volumes of air, a discovery that would eventually lead to the discovery of photosynthesis. Priestley also developed a "nitrous air test" to determine the "goodness of air". Using a pneumatic trough, he would mix nitrous air with a test sample, over water or mercury, and measure the decrease in volume—the principle of eudiometry. After a small history of the study of airs, he explained his own experiments in an open and sincere style. As an early biographer writes, "whatever he knows or thinks he tells: doubts, perplexities, blunders are set down with the most refreshing candour." Priestley also described his cheap and easy-to-assemble experimental apparatus; his colleagues therefore believed that they could easily reproduce his experiments. Faced with inconsistent experimental results, Priestley employed phlogiston theory. This, however, led him to conclude that there were only three types of "air": "fixed", "alkaline", and "acid". Priestley dismissed the burgeoning chemistry of his day. Instead, he focused on gases and "changes in their sensible properties", as had natural philosophers before him. He isolated carbon monoxide (CO), but apparently did not realise that it was a separate "air".

In 1777, Antoine Lavoisier had written Mémoire sur la combustion en général, the first of what proved to be a series of attacks on phlogiston theory; it was against these attacks that Priestley responded in 1783. While Priestley accepted parts of Lavoisier's theory, he was unprepared to assent to the major revolutions Lavoisier proposed: the overthrow of phlogiston, a chemistry based conceptually on elements and compounds, and a new chemical nomenclature. Priestley's original experiments on "dephlogisticated air" (oxygen), combustion, and water provided Lavoisier with the data he needed to construct much of his system; yet Priestley never accepted Lavoisier's new theories and continued to defend phlogiston theory for the rest of his life. Lavoisier's system was based largely on the quantitative concept that mass is neither created nor destroyed in chemical reactions (i.e., the conservation of mass). By contrast, Priestley preferred to observe qualitative changes in heat, color, and particularly volume. His experiments tested "airs" for "their solubility in water, their power of supporting or extinguishing flame, whether they were respirable, how they behaved with acid and alkaline air, and with nitric oxide and inflammable air, and lastly how they were affected by the electric spark.